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ExamsJEE MainChemistry

The compressibility factor for a real gas at high pressure is:

  1. 1 + RT/Pb
  2. 1
  3. 1 + Pb/RT
  4. 1 - Pb/RT

Correct answer: 1 + Pb/RT

Solution

At high pressure the molecular-volume term of the van der Waals equation dominates, giving Z = PV/RT = 1 + Pb/RT, i.e. Z > 1.

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