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The compressibility factor for a real gas at high pressure is:
- 1 + RT/Pb
- 1
- 1 + Pb/RT
- 1 - Pb/RT
Correct answer: 1 + Pb/RT
Solution
At high pressure the molecular-volume term of the van der Waals equation dominates, giving Z = PV/RT = 1 + Pb/RT, i.e. Z > 1.
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