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ExamsJEE MainChemistry

Using MO theory, predict which of the following species has the shortest bond length?

  1. O2+
  2. O2−
  3. O2²−
  4. O2²+

Correct answer: O2²+

Solution

Bond orders: O2+ = 2.5, O2- = 1.5, O2(2-) = 1.0, O2(2+) = 3.0. The highest bond order, O2(2+) with BO = 3, has the shortest bond length.

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