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ExamsJEE MainChemistry

Nitric oxide (NO) has a bond order of 2.5, whereas the nitrosonium ion (NO+) has a bond order of 3. Which statement correctly compares their bond lengths?

  1. The bond length of NO+ is the same as that of NO
  2. The bond length of NO is greater than the bond length of NO+
  3. The bond length of NO+ is greater than the bond length of NO
  4. No definite comparison of bond lengths can be made

Correct answer: The bond length of NO is greater than the bond length of NO+

Solution

A higher bond order indicates a stronger bond, which typically results in a shorter bond length. Since NO+ has a bond order of 3 compared to NO's bond order of 2.5, NO+ has a stronger bond and thus a shorter bond length.

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