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ExamsJEE MainChemistry

For any given series of spectral lines of atomic hydrogen, let Δν̄ = ν̄_max − ν̄_min be the difference in maximum and minimum frequencies in cm⁻¹. The ratio Δν̄_Lyman / Δν̄_Balmer is:

  1. 4: 1
  2. 9: 4
  3. 5: 4
  4. 27: 5

Correct answer: 9: 4

Solution

The ratio Δν̄_Lyman / Δν̄_Balmer is derived from the differences in energy levels involved in the transitions for each series. The Lyman series transitions occur from higher energy levels to n=1, while the Balmer series transitions go to n=2, resulting in a greater frequency range for the Lyman series, specifically leading to a ratio of 9:4 when calculated.

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