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ExamsJEE MainChemistry

Which of the following species exhibits a trigonal bipyramidal arrangement?

  1. XeO3F2
  2. XeO3F2
  3. FXeOSO2F
  4. [XeF8]2−

Correct answer: XeO3F2

Solution

In XeO3F2 the Xe atom forms three Xe=O and two Xe-F bonds with no lone pair, giving five electron domains and a trigonal bipyramidal shape. [XeF8]2- is square antiprismatic, not TBP.

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