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ExamsJEE MainChemistry

The standard reduction potentials for the following half-reactions are listed below: F2(g) + 2e− → 2F−(aq); E° = +2.85 V Cl2(g) + 2e− → 2Cl−(aq); E° = +1.36 V Br2(l) + 2e− → 2Br−(aq); E° = +1.06 V I2(s) + 2e− → 2I−(aq); E° = +0.53 V From these, identify the most powerful oxidizing agent and the most powerful reducing agent, respectively.

  1. F2 and I−
  2. Br2 and Cl−
  3. Cl2 and Br−
  4. Cl2 and I−

Correct answer: F2 and I−

Solution

F2 has the highest reduction potential (+2.85 V) so it is the strongest oxidising agent, and I- (from the lowest-E couple) is the strongest reducing agent. The pair is F2 and I-, not Cl2 and Br-.

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