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ExamsJEE AdvancedChemistry

The rate law for A + 2B -> P is d[P]/dt = k[A]²[B]. If A is taken in large excess, what is the observed order of the reaction?

  1. Zero
  2. 1
  3. 2
  4. 3

Correct answer: 1

Solution

If A is in large excess, [A]² is essentially constant and merges into k', giving rate = k'[B], a first order (pseudo-first order) reaction.

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