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ExamsJEE AdvancedChemistry

A first-order reaction is 75% complete in 72 minutes. Determine the time required for (i) 50% completion and (ii) 87.5% completion.

  1. 24, 96
  2. 36, 108
  3. 48, 120
  4. 72, 144

Correct answer: 36, 108

Solution

75% completion means two half-lives (each leaves half), so t1/2 = 36 min (=50% completion); 87.5% completion is three half-lives = 108 min.

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