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ExamsJEE AdvancedChemistry

When acetic anhydride reacts with excess ammonia, what is the organic product formed?

  1. CH3CONH2
  2. CH3CONHCH3
  3. CH3CN
  4. CH3COONH4

Correct answer: CH3CONH2

Solution

Acetic anhydride reacts with ammonia via nucleophilic acyl substitution to give acetamide (CH3CONH2) and acetic acid. There is no N-methylation since CH3 does not transfer from the carbonyl carbon.

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