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ExamsJEE AdvancedChemistry

Which of the following properties has a LOWER value for D2O compared to H2O?

  1. Density (g/mL) at 20 deg C
  2. Boiling point
  3. Dielectric constant at 20 deg C
  4. Latent heat of vaporisation at 20 deg C

Correct answer: Dielectric constant at 20 deg C

Solution

Although D2O has stronger intermolecular hydrogen bonds, its dielectric constant is marginally lower than H2O at 20 deg C (~78.25 vs ~80.1), making this the property that is LESS for D2O. All other listed properties — density, boiling point, and latent heat — are higher for D2O.

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