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ExamsJEE AdvancedChemistry

Identify the correct statement(s) among the following: (P) A catalyst does not change the enthalpy change (delta H) of a reaction. (Q) Increasing the concentration of a reactant always increases the rate of reaction. (R) An increase in temperature raises the rate of reaction mainly because of the increase in collision frequency among reactant molecules.

  1. Only P
  2. Only Q
  3. Only R
  4. None of these

Correct answer: Only P

Solution

P is correct: a catalyst affects kinetics, not thermodynamics. Q is false for zero-order reactions. R is false: the dominant effect of temperature is the increase in the fraction of molecules exceeding the activation energy (Boltzmann factor), not collision frequency.

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