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ExamsJEE AdvancedChemistry

Which of the following properties is NOT significantly affected by hydrogen bonding?

  1. Boiling point of H3PO4
  2. Viscosity of H2O2
  3. Basicity of maleic acid
  4. Acidic strength of o-hydroxybenzoic acid

Correct answer: Basicity of maleic acid

Solution

H3PO4 has an abnormally high boiling point due to intermolecular H-bonding. H2O2 has high viscosity due to strong H-bonding network. Salicylic acid (o-hydroxybenzoic acid) has enhanced acidity due to intramolecular H-bonding stabilizing the carboxylate. Maleic acid's basicity (proton acceptance) is not meaningfully linked to hydrogen bonding — this is an intrinsic electronic property.

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