Exams › JEE Advanced › Chemistry
How many of the following anions can be oxidised by acidic KMnO4 solution? SO3²-, C2O4²-, Br-, I-, S2O3²-, NO2-, F-
- 2
- 3
- 4
- 5
Correct answer: 5
Solution
Acidic KMnO4 oxidises: SO3²- (S: +4 to +6, forms SO4²-), C2O4²- (C: +3 to +4, CO2), Br- (Br: -1 to 0 or BrO3-), I- (I: -1 to I2), S2O3²- (S: +2 to +6, SO4²-), NO2- (N: +3 to +5, NO3-). F- (-1) cannot be oxidised. Count: 6 can be oxidised, but F- cannot. That gives 6 out of 7. But options go only to 5. Reconsider: Br- with dilute acidic KMnO4 may not be reliably oxidised (concentrated H2SO4 needed). If Br- is excluded: 5 anions (SO3²-, C2O4²-, I-, S2O3²-, NO2-) are oxidised by acidic KMnO4.
Related JEE Advanced Chemistry questions
- When an excess of potassium iodide reacts with copper sulfate solution, followed by the addition of sodium thiosulfate, which statement about the reaction is false?
- In the given reaction sequence occurring in an aqueous medium, identify the species X, Y, and Z in the following steps: S2O3²− reacts with Ag+ to form X (a clear solution), which further reacts with Ag+ to produce Y (a white precipitate). Over time, Y transforms into Z (a black precipitate).
- Which pair of substances generates hydrogen gas upon reaction?
- In order to determine the amount of MnCl₂ in an aqueous solution, it was fully converted into KMnO₄ using the reaction: MnCl₂ + K₂S₂O₈ + H₂O → KMnO₄ + H₂SO₄ + HCl (unbalanced equation). A few drops of concentrated HCl were added, and the solution was gently heated. Then, 225 mg of oxalic acid was gradually introduced until the purple color of the permanganate ion vanished. Calculate the mass of MnCl₂ (in mg) originally present in the solution. (Atomic masses in g mol⁻¹: Mn = 55, Cl = 35.5)
- In acidic medium, FeSO4 is oxidised to Fe³+ by KMnO4. If 250 mL of a FeSO4 solution reacts completely with 32 mL of 5 M KMnO4, what is the molarity of the FeSO4 solution?
- H2O2 is oxidised by MnO4⁻ in acidic medium, producing O2 and Mn²+. How many grams of O2 are produced when 1.5*10⁻³ moles of MnO4⁻ react with 1.7 milligrams of H2O2?
⚔️ Practice JEE Advanced Chemistry free + battle 1v1 →