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ExamsJEE AdvancedChemistry

The wave function for the 2s orbital of hydrogen is given by Psi = (1/(4 sqrt(2))) (1/a0)^(3/2) (2 - r/a0) exp(-r/(2 a0)), where a0 = 0.529 Angstrom is the Bohr radius. Identify the correct statement(s).

  1. The number of radial nodes is equal to three.
  2. The probability density of finding the electron is independent of direction.
  3. The probability density of finding the electron at the nucleus is non-zero.
  4. The radial node occurs at a distance 2a0 from the nucleus.

Correct answer: The probability density of finding the electron is independent of direction.

Solution

Radial nodes occur where the radial wavefunction equals zero (excluding infinity). Setting 2 - r/a0 = 0 gives r = 2a0: only one radial node, not three. The 2s orbital (l=0) has no angular part, so the probability density |Psi|² is spherically symmetric, i.e., independent of direction. At the nucleus (r=0): Psi = (1/(4 sqrt(2)))(1/a0)^(3/2)(2)(1) which is non-zero, so |Psi|² is non-zero at the nucleus. The radial node is at r=2a0. Correct statements: B, C, D.

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