Correct answer: 3.2×10^-19 J
The kinetic energy of the fastest electron is calculated as K.E. = E - W₀, where E is the energy of the incident photon and W₀ is the work function. Substituting the given values, K.E. = 6.2 eV - 4.2 eV = 2.0 eV, which converts to 3.2×10^-19 J. Thus, option A is correct.