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The pH of solution containing \( 0.10 M \) sodium acetate and \( 0.03 M \) acetic acid is: \( \left(p K_{a} \text { for } C H_{3} C O O H=4.57\right) \)
- 4.09
- 6.09
- 5.09
- 7.09
Correct answer: 5.09
Solution
This is an acetic acid/acetate buffer, so the Henderson–Hasselbalch equation applies: pH = pKa + log([A−]/[HA]). Since acetate is the conjugate base and is more concentrated than the acid, the pH should be slightly above 4.57, matching 5.09.
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