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In the Haber process for the industrial manufacturing of ammonia involving the reaction \( N_{2}(g)+3 H_{2}(g) \rightleftharpoons 2 N H_{3}(g) \) at 200atm pressure in the presence of a catalyst, a temperature of about \( 500^{\circ} \mathrm{C} \) is used. This is considered as optimum temperature for the process because:

  1. yield is maximum at this temperature
  2. catalyst is active only at this temperature
  3. energy needed for the reaction is easily obtained at this temperature
  4. rate of the catalytic reaction is fast enough while the yield is also appreciable for this exothermic reaction at this temperature

Correct answer: rate of the catalytic reaction is fast enough while the yield is also appreciable for this exothermic reaction at this temperature

Solution

The Haber process uses a temperature that balances two competing effects: lower temperatures favor ammonia formation at equilibrium, but they make the reaction too slow. Around 500°C, the catalyst gives a fast enough rate while the equilibrium yield remains acceptable.

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