In which of the following the hydration energy is higher than the lattice energy?
MgSO4
BaSO4
SrSO4
CaSO4
Correct answer: MgSO4
Solution
Hydration energy decreases down the group as ionic size increases, while lattice energy also decreases but at a slower rate. MgSO4 has the smallest cation, leading to higher hydration energy compared to its lattice energy.