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ExamsNEETChemistry

Hydrogen has an ionisation energy of 1311 kJ mol⁻¹ and for chlorine it is 1256 kJ mol⁻¹. Hydrogen forms H⁺(aq) ions but chlorine does not form Cl⁺(aq) ions because

  1. H⁺ has lower hydration enthalpy
  2. Cl⁺ has lower hydration enthalpy
  3. Cl has high electron affinity
  4. Cl has high electronegativity

Correct answer: Cl has high electron affinity

Solution

Chlorine has a high electron affinity, making it more likely to gain an electron and form Cl⁻ rather than lose an electron to form Cl⁺. This explains why Cl⁺(aq) ions are not formed.

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