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Value of van der Waals constant ‘a’ signifies intermolecular forces of attraction. Higher is the value of ‘a’, easier will be the liquefaction of gas.
- At high temperature and low pressure.
- Higher the critical temperature more easily will the gas liquify.
- Now since most easily liquefiable gas show larger deviation, NH3 will show maximum deviation from ideal behaviour.
- Density = PM / RT = 5 × 28 / 0.0821 × 500 = 3.41g/mL.
Correct answer: Now since most easily liquefiable gas show larger deviation, NH3 will show maximum deviation from ideal behaviour.
Solution
Option C is correct because NH3 has strong intermolecular hydrogen bonding, leading to significant deviation from ideal gas behavior and easier liquefaction.
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