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Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect ? (The Bohr radius is represented by a0). (1) The magnitude of the potential energy is double that of its kinetic energy on an average. (2) The probability density of finding the electron is maximum at the nucleus. (3) The total energy of the electron is maximum when it is at a distance a0 from the nucleus. (4) The electron can be found at a distance 2a0 from the nucleus.

  1. The magnitude of the potential energy is double that of its kinetic energy on an average.
  2. The probability density of finding the electron is maximum at the nucleus.
  3. The total energy of the electron is maximum when it is at a distance a0 from the nucleus.
  4. The electron can be found at a distance 2a0 from the nucleus.

Correct answer: The total energy of the electron is maximum when it is at a distance a0 from the nucleus.

Solution

For the 1s electron, virial theorem (|PE|=2*KE), max probability density at the nucleus, and finite probability at 2a0 are all correct. The incorrect statement is that total energy is maximum at distance a0 -- the total (orbital) energy is constant and independent of position, so option (3) is the wrong statement.

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