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ExamsJEE MainChemistry

A 0.1 molal aqueous solution of a weak acid is 30% ionized. If Kf for water is 1.86 °C/m, the freezing point of the solution will be:

  1. -0.18 °C
  2. -0.54 °C
  3. -0.36 °C
  4. -0.24 °C

Correct answer: -0.36 °C

Solution

The freezing point depression is given by ΔT = Kf × m, where m is the molality of the solution. Since the solution is 30% ionized, the effective molality is 0.3 × 0.1 = 0.03 m. Therefore, ΔT = 1.86 × 0.03 = 0.0558 °C. Since the solution is below the freezing point of water, the freezing point depression is negative.

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