Exams › JEE Main › Chemistry
Given Reaction Energy Change (in kJ) Li(s) → Li(g) 161 Li(g) → Li⁺(g) 520 1/2 F₂(g) → F(g) 77 F(g) + e⁻ → F⁻(g) (Electron gain enthalpy) Li⁺(g) + F⁻(g) → LiF(s) -1047 Li(s) + 1/2 F₂(g) → LiF(s) -617 Based on data provided, the value of electron gain enthalpy of fluorine would be:
- -300 kJ mol⁻¹
- -350 kJ mol⁻¹
- -328 kJ mol⁻¹
- -228 kJ mol⁻¹
Correct answer: -328 kJ mol⁻¹
Solution
The electron gain enthalpy of fluorine can be calculated by rearranging the given thermochemical equations to find the energy change associated with the formation of F⁻ from F(g). The correct value of -328 kJ mol⁻¹ is derived from the overall energy balance of the reactions involving lithium and fluorine.
Related JEE Main Chemistry questions
- Using the following thermochemical equations, determine the enthalpy of vaporisation of water: \[ \mathrm{H_2(g) + \tfrac{1}{2}O_2(g) \to H_2O(l)},\quad \Delta H = -286\ \text{kJ} \] \[ \mathrm{H_2(g) + \tfrac{1}{2}O_2(g) \to H_2O(g)},\quad \Delta H = -245.5\ \text{kJ} \]
- Given that the standard enthalpy of formation of NH$_3$ is $-46.0\ \text{kJ mol}^{-1}$, and the enthalpy of formation of H$_2$ from gaseous atoms is $-436\ \text{kJ mol}^{-1}$ while that of N$_2$ from gaseous atoms is $-712\ \text{kJ mol}^{-1}$, what is the average N–H bond enthalpy in NH$_3$?
- Using the following bond dissociation data, determine the enthalpy change for the conversion $8S(s) + \tfrac32 S_8(g)$.
- Using the bond enthalpies given below, determine the enthalpy change for the hydrogenation reaction shown: H–H bond energy = 431.37 kJ mol$^{-1}$ C–C bond energy = 606.10 kJ mol$^{-1}$ C–H bond energy = 336.49 kJ mol$^{-1}$ C–H bond energy = 410.50 kJ mol$^{-1}$ $C=C + H–H \rightarrow H–C–C–H$ What is the enthalpy change for this reaction?
- For a given reversible reaction, both enthalpy change ($\Delta H$) and entropy change ($\Delta S$) are positive. If $T_1$ denotes the equilibrium temperature, under which condition will the reaction be spontaneous?
- For the spontaneous reaction $2C_2H_6(g) + 25O_2(g) \rightarrow 16CO_2(g) + 18H_2O(g)$, what are the signs of $\Delta H$, $\Delta S$, and $\Delta G$ in that order?
⚔️ Practice JEE Main Chemistry free + battle 1v1 →