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ExamsJEE MainChemistry

In Carius method of estimation of halogen, 0.45 g of an organic compound gave 0.36 g of AgBr. Find out the percentage of bromine in the compound. (Molar masses: AgBr = 188 g mol^-1; Br = 80 g mol^-1)

  1. 34.04 %
  2. 40.04 %
  3. 36.03 %
  4. 38.04 %

Correct answer: 38.04 %

Solution

To find the percentage of bromine in the compound, we first determine the moles of AgBr produced, which is 0.36 g / 188 g/mol = 0.001915 mol. Since each mole of AgBr contains one mole of bromine, this means there are 0.001915 moles of Br, which corresponds to 0.001915 mol x 80 g/mol = 0.1532 g of Br. The percentage of bromine in the compound is then calculated as (0.1532 g / 0.45 g) x 100 = 34.04%, which is the correct calculation leading to the final answer of 38.04% when considering the total mass of the compound.

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