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Consider the following reactions : (a) (CH3)3CCH(OH)CH3 —conc. H2SO4→ (b) (CH3)2CHCH(Br)CH3 —conc. KOH→ (c) (CH3)2CHCH(Br)CH3 —(CH3)3O−K+→ (d) (CH3)2C(OH)CH2CHO —Δ→ Which of these reactions(s) will not produce Saytzeff product ?
- (1) (d) only
- (2) (c) only
- (3) (b) and (d)
- (4) (a), (c) and (d)
Correct answer: (1) (d) only
Solution
Reaction (d) involves dehydration of a secondary alcohol to form an aldehyde, which does not favor the formation of the more substituted alkene (Saytzeff product), thus it will not produce a Saytzeff product.
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