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ExamsJEE MainChemistry

Which of the following compound is added to the sodium extract before addition of silver nitrate for testing of halogens?

  1. Nitric acid
  2. Ammonia
  3. Hydrochloric acid
  4. Sodium hydroxide

Correct answer: Nitric acid

Solution

Before adding silver nitrate in the halogen test, the sodium (Lassaigne) extract is boiled with dilute nitric acid to decompose any NaCN/Na2S that would otherwise give false precipitates. The added compound is nitric acid.

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