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Which of the following compound is added to the sodium extract before addition of silver nitrate for testing of halogens?
- Nitric acid
- Ammonia
- Hydrochloric acid
- Sodium hydroxide
Correct answer: Nitric acid
Solution
Before adding silver nitrate in the halogen test, the sodium (Lassaigne) extract is boiled with dilute nitric acid to decompose any NaCN/Na2S that would otherwise give false precipitates. The added compound is nitric acid.
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