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The correct statement about B2H6 is:
(1) Terminal B–H bonds have less p-character when compared to bridging bonds.
(2) The two B–H–B bonds are not of same length.
(3) All B–H–B angles are of 120°
(4) Its fragment, BH3, behaves as a Lewis base
- (1)
- (2)
- (3)
- (4)
Correct answer: (1)
Solution
Terminal B–H bonds in B2H6 have a higher p-character compared to bridging bonds due to their different bonding environments; terminal bonds are more localized while bridging bonds involve more orbital overlap, leading to a difference in hybridization.
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