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The reaction of propene with HOCl (Cl2 + H2O) proceeds through the intermediate:
(1) CH3–CH2–CH2–OH
(2) CH3–CH+–CH2–Cl
(3) CH3–CH(OH)–CH2+
(4) CH3–CHCl–CH2+
- CH3–CH2–CH2–OH
- CH3–CH+–CH2–Cl
- CH3–CH(OH)–CH2+
- CH3–CHCl–CH2+
Correct answer: CH3–CH+–CH2–Cl
Solution
The correct option, CH3–CH+–CH2–Cl, represents a carbocation intermediate formed during the electrophilic addition of HOCl to propene, where the double bond reacts with the electrophile, leading to the formation of a positively charged carbon atom.
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