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ExamsJEE MainChemistry

The reaction of propene with HOCl (Cl2 + H2O) proceeds through the intermediate: (1) CH3–CH2–CH2–OH (2) CH3–CH+–CH2–Cl (3) CH3–CH(OH)–CH2+ (4) CH3–CHCl–CH2+

  1. CH3–CH2–CH2–OH
  2. CH3–CH+–CH2–Cl
  3. CH3–CH(OH)–CH2+
  4. CH3–CHCl–CH2+

Correct answer: CH3–CH+–CH2–Cl

Solution

The correct option, CH3–CH+–CH2–Cl, represents a carbocation intermediate formed during the electrophilic addition of HOCl to propene, where the double bond reacts with the electrophile, leading to the formation of a positively charged carbon atom.

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