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Which method is most suitable for preparing alkyl fluorides?
- Finkelstein reaction
- Swarts reaction
- Free-radical fluorination
- Sandmeyer reaction
Correct answer: Swarts reaction
Solution
The Swarts reaction treats an alkyl chloride/bromide with a metallic fluoride (AgF, Hg2F2, CoF2, SbF3) to give the alkyl fluoride, e.g. CH3Br + AgF -> CH3F + AgBr. Free-radical fluorination is too violent/uncontrolled to be useful.
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