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ExamsJEE MainChemistry

Which method is most suitable for preparing alkyl fluorides?

  1. Finkelstein reaction
  2. Swarts reaction
  3. Free-radical fluorination
  4. Sandmeyer reaction

Correct answer: Swarts reaction

Solution

The Swarts reaction treats an alkyl chloride/bromide with a metallic fluoride (AgF, Hg2F2, CoF2, SbF3) to give the alkyl fluoride, e.g. CH3Br + AgF -> CH3F + AgBr. Free-radical fluorination is too violent/uncontrolled to be useful.

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