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ExamsJEE MainChemistry

Arrange the following carbocations in decreasing order of stability: I. CH2=CH–CH2+ II. CH3–CH2–CH2+ III. C6H5–CH2+

  1. I > II > III
  2. II > III > I
  3. III > II > I
  4. III > I > II

Correct answer: III > I > II

Solution

C6H5-CH2+ (benzyl) is most stabilised by ring resonance, CH2=CH-CH2+ (allyl) is resonance-stabilised, and CH3-CH2-CH2+ is an unstabilised primary cation. Order: III > I > II (index 3).

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