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ExamsJEE MainChemistry

Which one of the following diols undergoes periodate cleavage with HIO4 to give two separate fragments?

  1. 1,3-hexanediol
  2. 2,4-hexanediol
  3. 1,6-hexanediol
  4. 3,4-hexanediol

Correct answer: 3,4-hexanediol

Solution

3,4-hexanediol has hydroxyl groups on adjacent carbon atoms, allowing periodate to cleave the carbon-carbon bond between them, resulting in two separate fragments. In contrast, the other diols do not have the necessary structural arrangement for this type of cleavage.

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