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ExamsJEE MainChemistry

In the Wurtz–Fittig reaction, which pair of compounds undergoes condensation?

  1. Two molecules of aryl halides
  2. One molecule each of an aryl halide and an alkyl halide
  3. One molecule each of an aryl halide and phenol
  4. Two molecules of aryl halides

Correct answer: One molecule each of an aryl halide and an alkyl halide

Solution

The Wurtz-Fittig reaction couples an aryl halide with an alkyl halide using sodium in dry ether to give an alkylarene (e.g. C6H5Br + CH3Br + 2Na -> C6H5CH3). It is the mixed aryl/alkyl coupling.

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