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ExamsJEE MainChemistry

When carbon dioxide gas is passed over red-hot coke, part of it is converted into carbon monoxide. If 0.5 L of CO₂ is passed over red-hot coke and the total volume of the resulting gaseous mixture becomes 700 mL, what is the composition of the gas mixture at STP?

  1. CO₂ = 300 mL; CO = 400 mL
  2. CO₂ = 400 mL; CO = 700 mL
  3. CO₂ = 200 mL; CO = 500 mL
  4. CO₂ = 350 mL; CO = 350 mL

Correct answer: CO₂ = 300 mL; CO = 400 mL

Solution

If x mL CO2 reacts, total gas = (500 - x) + 2x = 500 + x = 700, so x = 200. Remaining CO2 = 300 mL and CO = 400 mL, not 200/500.

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