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A hydrogen atom has its electron in the nth orbital. Electromagnetic radiation of wavelength 90 nm is incident on it and ionises the atom. The kinetic energy of the ejected electron is 10.4 eV. Find the value of n. (Use hc = 1242 eV nm)
- 1
- 2
- 3
- 4
Correct answer: 2
Solution
The photon supplies energy hc/lambda = 1242/90 = 13.8 eV. This energy must ionise the electron (overcoming its binding energy |Eₙ|) and give it kinetic energy 10.4 eV. So |Eₙ| = 13.8 - 10.4 = 3.4 eV. Using Eₙ = -13.6/n²: 3.4 = 13.6/n² -> n² = 4 -> n = 2.
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