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ExamsJEE AdvancedGeneral

The desired product X can be prepared by reacting the major product of the reactions in LIST-I with one or more appropriate regents in LIST-II. (given, order of migratory aptitude: aryl > alkyl > hydrogen) Ph Me Ph O X OH LIST-I LIST-II P. HO Ph Ph Me Me OH + H 2 SO 4 1. l 2 , NaOH Q. H 2 N Ph Ph H Me OH + HNO 2 2. [Ag(NH 3 ) 2 ]OH R. HO Ph Me Ph Me OH + H 2 SO 4 3. Fehling solution S. Br Ph Ph H Me OH + AgNO 3 4. HCHO, NaOH 5. NaOBr The correct option is :

  1. P → 1; Q → 2,3; R → 1,4; S → 2,4
  2. P → 1,5; Q → 3,4; R → 4,5; S → 3
  3. P → 1,5; Q → 3,4; R → 5; S → 2,4
  4. P → 1,5; Q → 2,3; R → 1,5; S → 2,3 CAREER POINT CAREER POINT , CP Tower, IPIA, Road No.1, Kota (Raj.), : 0744-6630500 | www.ecareerpoint.com Email: info@cpil.in Page # 27 Paper-2

Correct answer: P → 1,5; Q → 2,3; R → 1,5; S → 2,3 CAREER POINT CAREER POINT , CP Tower, IPIA, Road No.1, Kota (Raj.), : 0744-6630500 | www.ecareerpoint.com Email: info@cpil.in Page # 27 Paper-2

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