Exams › JEE Advanced › General

Match the four starting materials ( P, Q, R, S ) given in List-I with the corresponding reaction schemes (I, II, III, IV) provided in List-II and select the correct answer using the code given below the lists. List – I List – II P. H H 1. Scheme I (i) KMnO 4 . HO Θ . heat (ii) H ⊕ , H 2 O (iii) SOCl 2 (iv) NH 3 C 7 H 6 N 2 O 3 ? Q. OH OH 2. Scheme II (i) Sn/HCl (ii) CH 3 COCl (iii) conc.H 2 SO 4 (iv) HNO 3 (v) dil.H 2 SO 4 , heat (vi) HO Θ C 6 H 6 N 2 O 2 ? CAREER POINT CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.) Ph.: 0744-6630500 www.ecareerpoint.com Email: info@cpil.in 34 / 54 Paper-2 [ CODE – 05 ] R. NO 2 3. Scheme III (i) red hot iron, 873 K (ii) fuming HNO 3, H 2 SO 4 , heat (iii) H 2 S.NH 3 (iv) NaNO 2 , H 2 SO 4 (v) hydrolysis C 6 H 5 NO 3 ? S. NO 2 CH 3 4. Scheme IV (i) conc. H 2 SO 4 , 60°C (ii) conc. HNO 3 , conc. H 2 SO 4 (iii) dil. H 2 SO 4 , heat C 6 H 5 NO 4 ? Codes : P Q R S

1. 1 4 2 3
2. 3 1 4 2
3. 3 4 2 1
4. 4 1 3 2

Correct answer: 3 4 2 1

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