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ExamsJEE AdvancedChemistry

Transition metals form complexes far more readily than the s- and p-block (representative) elements mainly because:

  1. vacant d-orbitals of suitable energy are available for accepting electron pairs
  2. transition elements do not exhibit variable oxidation states
  3. all the d-electrons are completely paired
  4. f-orbitals are available for bond formation

Correct answer: vacant d-orbitals of suitable energy are available for accepting electron pairs

Solution

Transition metals have small size, high charge density and energetically accessible vacant d-orbitals, enabling them to accept electron pairs from ligands and form coordinate bonds.

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