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ExamsJEE AdvancedChemistry

In one molecule of pyrophosphoric acid (H4P2O7), what are the numbers of P-OH bonds, P=O bonds, and P-O-P bridges respectively?

  1. (1) 3, 3 and 3
  2. (2) 2, 4 and 1
  3. (3) 4, 2 and 0
  4. (4) 4, 2 and 1

Correct answer: (4) 4, 2 and 1

Solution

H4P2O7 has two PO4 tetrahedra sharing one bridging O (one P-O-P), four ionizable OH groups (four P-OH), and one terminal P=O on each phosphorus (two P=O).

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