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ExamsJEE AdvancedChemistry

In a 7.0 L evacuated chamber, 0.50 mol H2 and 0.50 mol I2 react at 427 deg C according to H2(g) + I2(g) <=> 2HI(g), with Kc = 49. What is the partial pressure (in atm) of HI in the equilibrium mixture?

  1. 6.385
  2. 12.77
  3. 40.768
  4. 646.58

Correct answer: 6.385

Solution

Solving gives x = 0.0556 mol per unit so [HI] forms 0.778 mol; using PV = nRT at 700 K and 7 L gives P(HI) ~ 6.39 atm.

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