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ExamsJEE AdvancedChemistry

Which of the following reactions represents an example of the reduction of a calcined or roasted ore to obtain the metal?

  1. Bauxite ore + Na2CO3 (fused) -> NaAlO2
  2. Ag2S + NaCN <=> Na[Ag(CN)2] + Na2S
  3. ZnO + C -> Zn + CO
  4. CuSO4(aq.) + Zn dust -> ZnSO4 + Cu

Correct answer: ZnO + C -> Zn + CO

Solution

ZnS (zinc blende) is first roasted to ZnO (calcined ore), then ZnO is reduced by coke (C) at high temperature: ZnO + C -> Zn + CO. This is the classic example of reduction of a roasted/calcined ore. The other options represent fusion, leaching (hydrometallurgy), and cementation respectively.

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