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ExamsJEE AdvancedChemistry

In the reaction BeCl2 + LiAlH4 → X + LiCl + AlCl3, compound X is formed. How many 3-centre 4-electron (3c-4e) bonds are present in the monomer form of X?

  1. 1
  2. 2
  3. 3
  4. 0

Correct answer: 0

Solution

The reaction gives X = BeH2. In the monomer form, BeH2 is a linear molecule (Be is sp hybridized) with two normal 2c-2e Be-H bonds. The 3c-2e bonds appear in the polymer/dimer form (bridging H), and 3c-4e bonds are seen in hypervalent molecules like PCl5 axial bonds. The monomer BeH2 has zero 3c-4e bonds.

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