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ExamsJEE AdvancedChemistry

In the Ellingham diagram, carbon-based reduction of a metal oxide M'O to give metal M' and the acidic oxide of carbon (CO2) becomes thermodynamically feasible above which temperature?

  1. 2100 K
  2. 2550 K
  3. 1300 K
  4. 600 K

Correct answer: 1300 K

Solution

The Ellingham diagram shows that the free energy line for C + O2 -> CO2 (which slopes upward positively) crosses below several metal oxide lines near 1300 K, making reduction of M'O by carbon to give M' and CO2 thermodynamically spontaneous above that temperature.

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