StreakPeaked· Practice

ExamsJEE AdvancedChemistry

Which of the following compounds releases O2 gas upon hydrolysis?

  1. Pb3O4
  2. KO2
  3. Na2O2
  4. Li2O2

Correct answer: KO2

Solution

KO2 is potassium superoxide, containing the O2⁻ ion. It reacts with water: 4KO2 + 2H2O -> 4KOH + 3O2. This liberates oxygen gas. Na2O2 (sodium peroxide) reacts with water to give NaOH and H2O2, not O2 directly (H2O2 can decompose to O2 slowly but the primary product is H2O2). Li2O2 and Na2O2 give peroxide ions. Pb3O4 is a mixed oxide (PbO + PbO2) and does not liberate O2 on hydrolysis. Only KO2 directly produces O2 upon hydrolysis.

Related JEE Advanced Chemistry questions

⚔️ Practice JEE Advanced Chemistry free + battle 1v1 →