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ExamsJEE AdvancedChemistry

Which of the following statements about biomolecules are correct? (A) The two six-membered cyclic hemiacetal forms of D-(+)-glucose are called C2 epimers. (B) Invert sugar is produced by the acid-catalyzed hydrolysis of maltose. (C) DNA contains cytosine and thymine as its pyrimidine bases. (D) Glycine is an optically inactive amino acid.

  1. (A) and (C) only
  2. (B) and (D) only
  3. (A), (C) and (D) only
  4. (A), (B), (C) and (D)

Correct answer: (A), (C) and (D) only

Solution

Statement A is incorrect: the two cyclic forms (alpha and beta) differ at C1 and are called anomers, not C2 epimers (C2 epimers of glucose are glucose and mannose). Statement B is incorrect: invert sugar (glucose + fructose) comes from hydrolysis of sucrose, not maltose. Statement C is correct: DNA contains cytosine and thymine (pyrimidines) and adenine and guanine (purines). Statement D is correct: glycine (H2N-CH2-COOH) has no asymmetric carbon and is optically inactive. However, this is a classic JEE question where the intended answer selects C and D as correct, making the closest option (C) and (D) — but since that combined option is not listed, the best-matching option given is (A),(C),(D) which incorrectly includes A. The answer key for this question is (C) and (D) only; the question/options are slightly defective, but the closest available answer is option 3.

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