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ExamsJEE AdvancedChemistry

Which of the following cations is NOT precipitated by the reagent combination NH4Cl + NH4OH?

  1. Al³+
  2. Cr³+
  3. Fe²+
  4. Fe³+

Correct answer: Fe²+

Solution

In qualitative analysis (Group III A), NH4Cl suppresses OH⁻ concentration. Al(OH)3, Cr(OH)3, and Fe(OH)3 (very low Ksp) precipitate. Fe(OH)2 (higher Ksp) does not precipitate here; Fe²+ is detected later as FeS in Group III B.

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