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ExamsJEE AdvancedChemistry

Which of the following is NOT a reducing disaccharide?

  1. Cellobiose
  2. Lactose
  3. Maltose
  4. Sucrose

Correct answer: Sucrose

Solution

Cellobiose, lactose, and maltose all have one free anomeric carbon (C1-OH in glucose unit) that can open to the aldehyde form and reduce Fehling's/Tollens' reagent. Sucrose is formed by a 1,2-glycosidic bond between C1 of glucose and C2 of fructose, blocking both anomeric carbons. Therefore sucrose cannot open to an aldehyde form and is a non-reducing sugar.

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