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ExamsJEE AdvancedChemistry

Which reason below does not play a role in roasting sulphide ores to oxides instead of directly reducing them with carbon?

  1. Metal sulphides are more thermodynamically stable compared to CS$_2$.
  2. CO$_2$ has greater thermodynamic stability than CS$_2$.
  3. Metal sulphides are not as stable as their oxide counterparts.
  4. CO$_2$ is less volatile than CS$_2$.
  5. Metal sulphides are not as stable as their oxide counterparts.

Correct answer: Metal sulphides are not as stable as their oxide counterparts.

Solution

Roasting sulphide ores converts them into oxides, which are generally easier to reduce. The option stating that metal sulphides are not as stable as their oxide counterparts is not a reason for roasting; it is a broad statement and not the specific thermodynamic/practical basis used here.

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